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The NaOH (caustic soda) and elevated temperature cause Fe 3 O 4 (black oxide) to form on the surface of the metal instead of Fe 2 O 3 (red oxide; rust). While it is physically denser than red oxide, the fresh black oxide is porous, so oil is then applied as post treatment to the heated part, which seals it by "sinking" into it.
It does provide good rust resistance, which is improved with oil. "Rust bluing" and "fume bluing" provide the best rust and corrosion resistance as the process continually converts any metal that is capable of rusting into magnetite (Fe 3 O 4). Treating with an oiled coating enhances the protection offered by the bluing.
Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the mineral pair forms a buffer that can control how oxidizing its environment is (the oxygen fugacity). This buffer is known as the hematite-magnetite or HM buffer.
Mill scale is a complex oxide that contains around 70% iron with traces of nonferrous metals and alkaline compounds. Reduced iron powder may be obtained by conversion of mill scale into a single highest oxide i.e. hematite (Fe 2 O 3) followed by reduction with hydrogen.
Iron(III) oxide was the most common magnetic particle used in all types of magnetic storage and recording media, including magnetic disks (for data storage) and magnetic tape (used in audio and video recording as well as data storage). Its use in computer disks was superseded by cobalt alloy, enabling thinner magnetic films with higher storage ...
Rust converters are chemical solutions or primers that can be applied directly to an iron or iron alloy surface to convert iron oxides into a protective chemical barrier. These compounds interact with iron oxides, especially iron(III) oxide , converting them into an adherent black layer ( black oxide ) that is more resistant to moisture and ...
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