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The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
When these fluctuations were explained as a manifestation of changes in atmospheric pressure, the science of meteorology was born. Over time, 760 millimeters of mercury at 0 °C came to be regarded as the standard atmospheric pressure. In honour of Torricelli, the torr was defined as a unit of pressure equal to one millimeter of mercury at 0 °C.
At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [1] 760 Torr, 101.325 kPa, or 14.69595 psi. For example, at any given temperature, methyl chloride has the highest vapor pressure of any of the liquids in the chart.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Pressure may also be expressed in terms of standard atmospheric pressure; the unit atmosphere (atm) is equal to this pressure, and the torr is defined as 1 ⁄ 760 of this. Manometric units such as the centimetre of water , millimetre of mercury , and inch of mercury are used to express pressures in terms of the height of column of a particular ...
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
The conversion equations depend on the temperature at which the conversion is wanted (usually about 20 to 25 degrees Celsius). At an ambient air pressure of 1 atmosphere (101.325 kPa), the general equation is: = / ()