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In organic chemistry, the cycloalkanes (also called naphthenes, but distinct from naphthalene) are the monocyclic saturated hydrocarbons. [1] In other words, a cycloalkane consists only of hydrogen and carbon atoms arranged in a structure containing a single ring (possibly with side chains ), and all of the carbon-carbon bonds are single .
Gasoline synthesis: The Reactor 2 product gas is next fed to Reactor 3, the third reactor containing the catalyst for conversion of DME to hydrocarbons including paraffins , aromatics, naphthenes (cycloalkanes) and small amounts of olefins , typically with the carbon number ranging from 6 to 10.
Gasoline synthesis: The Reactor 2 product gas is next fed to Reactor 3, the third reactor containing the catalyst for conversion of DME to hydrocarbons including paraffins , aromatics, naphthenes (cycloalkanes) and small amounts of olefins , mostly from C 6 (number of carbon atoms in the hydrocarbon molecule) to C 10.
As also depicted in Figure 2, the cycloalkanes (naphthenes) formed by the initial breakup of the large molecules are further converted to aromatics such as benzene, toluene, and xylenes, which boil in the gasoline boiling range and have much higher octane ratings than alkanes.
As of alkanes, they first dehydrogenate to olefins, then form rings at the place of the double bond, becoming cycloalkanes, and finally gradually lose hydrogen to become aromatic hydrocarbons. [ 4 ] For cyclohexane, cyclohexene, and cyclohexadiene, dehydrogenation is the conceptually simplest pathway for aromatization.
The major types of hydrocarbons present in crude oils consist of 1) normal paraffins, 2) branched paraffins (iso-paraffins), 3) cycloparaffins (naphthenes) and 4) aromatics. 3. General Base Oil Classification
However, both the dehydrogenation of naphthenes and the dehydrocyclization of paraffins produce hydrogen. The overall net production of hydrogen in the catalytic reforming of petroleum naphthas ranges from about 50 to 200 cubic meters of hydrogen gas (at 0 °C and 1 atm) per cubic meter of liquid naphtha feedstock.
Simple cycloalkanes have a prefix "cyclo-" to distinguish them from alkanes. Cycloalkanes are named as per their acyclic counterparts with respect to the number of carbon atoms in their backbones, e.g., cyclopentane (C 5 H 10 ) is a cycloalkane with 5 carbon atoms just like pentane (C 5 H 12 ), but they are joined up in a five-membered ring.