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Liquid crystallinity in polymers may occur either by dissolving a polymer in a solvent (lyotropic liquid-crystal polymers) or by heating a polymer above its glass or melting transition point (thermotropic liquid-crystal polymers). [6] Liquid-crystal polymers are present in melted/liquid or solid form. [7]
Polymeric liquid crystals are similar to monomeric liquid crystals used in displays. [1] Both have dielectric anitroscopy, or the ability to change directions and absorb or transmit light depending on electric fields. Polymeric liquid crystals form long head-to-tail or side chain polymers, which are woven in thick mats and therefore have high ...
Liquid crystal color transitions are used on many aquarium and pool thermometers as well as on thermometers for infants or baths. [84] Other liquid crystal materials change color when stretched or stressed. Thus, liquid crystal sheets are often used in industry to look for hot spots, map heat flow, measure stress distribution patterns, and so on.
Polymers can crystallize through a variety of different regimes and unlike simple molecules, the polymer crystal lamellae have two very different surfaces. The two most prominent theories in polymer crystallization kinetics are the Avrami equation and Lauritzen-Hoffman Growth Theory.
The phase transition temperature of an azo-liquid crystalline elastomer can be reduced due to the trans-cis isomerization of the azobenzenes during UV-irradiation and thus the liquid crystalline phase can be destroyed isothermally. For liquid crystalline elastomers with a high azo-concentration, a light-responsive change of the sample's length ...
A highly viscous cubic phase gel made of polysorbate 80, water, and liquid paraffin. Lyotropic liquid crystals result when amphiphiles, which are both hydrophobic and hydrophilic, dissolve into a solution that behaves both like a liquid and a solid crystal. This liquid crystalline mesophase includes everyday mixtures like soap and water. [1] [2]
Now, however, liquid crystals have also found applications as liquid-crystal displays, liquid crystal tunable filters, and liquid crystal thermometers. Active liquid crystals are another example of soft materials, where the constituent elements in liquid crystals can self-propel. [48] Polymers have found diverse applications, from the natural ...
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...