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The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant (Schwarz theorem).
The thermodynamic square can also be used to find the first-order derivatives in the common Maxwell relations.The following procedure should be considered: Looking at the four corners of the square and make a shape with the quantities of interest.
In a paramagnetic system, that is, a system in which the magnetization vanishes without the influence of an external magnetic field, assuming some simplifying assumptions (such as the sample system being ellipsoidal), one can derive a few compact thermodynamic relations. [4]
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In statistical physics and thermodynamics, the Maxwell construction is a method for addressing the physically unrealistic aspects of certain models of phase transitions. Named for physicist James Clerk Maxwell , it considers areas of regions on phase diagrams .
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Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, electric and magnetic circuits.
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