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Martensite has a lower density than austenite, so that the martensitic transformation results in a relative change of volume. [4] Of considerably greater importance than the volume change is the shear strain, which has a magnitude of about 0.26 and which determines the shape of the plates of martensite. [5]
The iron-chromium phase diagram shows that up to about 13% Cr, the steel undergoes successive transformations upon cooling from the liquid phase from ferritic α phase to austenitic γ phase and back to α. When some carbon is present, and if cooling occurs quickly, some of the austenite will transform into martensite.
Duplex stainless is widely used in the industry because it possesses excellent oxidation resistance but can have limited toughness due to its large ferritic grain size, and they have hardened, and embrittlement tendencies at temperatures ranging from 280 to 500 °C, especially at 475 °C, where spinodal decomposition of the supersaturated solid ...
Austenite is slightly undercooled when quenched below Eutectoid temperature. When given more time, stable microconstituents can form: ferrite and cementite. Coarse pearlite is produced when atoms diffuse rapidly after phases that form pearlite nucleate. This transformation is complete at the pearlite finish time (P f).
At high cooling rates, the material will transform from austenite to martensite which is much harder and will generate cracks at much lower strains. The volume change (martensite is less dense than austenite) [9] can generate stresses as well. The difference in strain rates of the inner and outer portion of the part may cause cracks to develop ...
Further excessive heat-treatment brings about the decomposition of the martensite and reversion to austenite. Newer compositions of maraging steels have revealed other intermetallic stoichiometries and crystallographic relationships with the parent martensite, including rhombohedral and massive complex Ni 50 (X,Y,Z) 50 (Ni 50 M 50 in simplified ...
Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite. It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
Austenitic stainless steel is one of the five families of stainless steel (along with ferritic, martensitic, duplex and precipitation hardened). [1] Its primary crystalline structure is austenite (face-centered cubic). Such steels are not hardenable by heat treatment and are essentially non-magnetic. [2]