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Scheme of a molten-carbonate fuel cell. Molten-carbonate fuel cells (MCFCs) are high-temperature fuel cells that operate at temperatures of 600 °C and above.. Molten carbonate fuel cells (MCFCs) were developed for natural gas, biogas (produced as a result of anaerobic digestion or biomass gasification), and coal-based power plants for electrical utility, industrial, and military applications.
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) [1] into electricity through a pair of redox reactions. [2] Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction ...
Trona (trisodium hydrogendicarbonate dihydrate, also sodium sesquicarbonate dihydrate, Na 2 CO 3 ·NaHCO 3 ·2H 2 O) is a non-marine evaporite mineral. [4] [6] It is mined as the primary source of sodium carbonate in the United States, where it has replaced the Solvay process used in most of the rest of the world for sodium carbonate production.
A unitized regenerative fuel cell (URFC) is a fuel cell based on the proton exchange membrane which can do the electrolysis of water in regenerative mode and function in the other mode as a fuel cell recombining oxygen and hydrogen gas to produce electricity.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Hard water usually contains calcium or magnesium ions. Sodium carbonate is used for removing these ions and replacing them with sodium ions. [16] Sodium carbonate is a water-soluble source of carbonate. The calcium and magnesium ions form insoluble solid precipitates upon treatment with carbonate ions:
The conversion of sodium carbonate to sodium hydroxide was superseded entirely by the chloralkali process, which produces sodium hydroxide in a single process. Sodium hydroxide is also produced by combining pure sodium metal with water. The byproducts are hydrogen gas and heat, often resulting in a flame. 2 Na(s) + 2 H 2 O(l) → 2 NaOH(aq) + H ...
The ammonia from reaction (III) is recycled back to the initial brine solution of reaction (I). The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts: