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  2. Hydrogen chloride - Wikipedia

    en.wikipedia.org/wiki/Hydrogen_chloride

    The compound hydrogen chloride has the chemical formula HCl and as such is a hydrogen ... The states are characterized by the rotational quantum number J = 0, 1, 2 ...

  3. Principal quantum number - Wikipedia

    en.wikipedia.org/wiki/Principal_quantum_number

    The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals .

  4. Quantum number - Wikipedia

    en.wikipedia.org/wiki/Quantum_number

    In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system. To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantum numbers includes the principal, azimuthal, magnetic, and spin quantum numbers. To describe other ...

  5. 18-electron rule - Wikipedia

    en.wikipedia.org/wiki/18-electron_rule

    The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five (n−1)d orbitals, one ns orbital, and three np orbitals, where n is the principal quantum number. These orbitals can collectively accommodate 18 electrons as either bonding or non-bonding electron pairs.

  6. List of equations in quantum mechanics - Wikipedia

    en.wikipedia.org/wiki/List_of_equations_in...

    2.5 Hydrogen atom. 3 See also. ... m j = total angular momentum magnetic quantum number; ... n = principal quantum number; e = electron charge;

  7. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    However the multiplicity equals the number of spin orientations only if S ≤ L. When S > L there are only 2L+1 orientations of total angular momentum possible, ranging from S+L to S-L. [ 2 ] [ 3 ] The ground state of the nitrogen atom is a 4 S state, for which 2S + 1 = 4 in a quartet state, S = 3/2 due to three unpaired electrons.

  8. Selection rule - Wikipedia

    en.wikipedia.org/wiki/Selection_rule

    The general principle is that the symmetry of the excited state is obtained as the direct product of the symmetries of the component wave functions. [15] In rovibronic transitions, the excited states involve three wave functions. The infrared spectrum of hydrogen chloride gas shows rotational fine structure superimposed on the vibrational ...

  9. Bohr model - Wikipedia

    en.wikipedia.org/wiki/Bohr_model

    The orbits in which the electron may travel are shown as grey circles; their radius increases as n 2, where n is the principal quantum number. The 3 → 2 transition depicted here produces the first line of the Balmer series, and for hydrogen (Z = 1) it results in a photon of wavelength 656 nm (red light).