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The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO 2. It is the peroxide (O 2 2− ) salt of Ca 2+ . Commercial samples can be yellowish, but the pure compound is white.
Peroxynitrite can be prepared by the reaction of superoxide with nitric oxide: [1] [2] [3] NO + O − 2 → NO(O 2) −. It is prepared by the reaction of hydrogen peroxide with nitrite: [4] H 2 O 2 + NO − 2 → ONOO − + H 2 O. Its presence is indicated by the absorbance at 302 nm (pH 12, ε 302 = 1670 M −1 cm −1).
The overall chemical reaction is: CO 2 + Ca(OH) 2 → CaCO 3 + H 2 O + heat (in the presence of water) Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction. [5]
Sodium peroxide is an inorganic compound with the formula Na 2 O 2.This yellowish solid is the product of sodium ignited in excess oxygen. [3] It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na 2 O 2 ·2H 2 O 2 ·4H 2 O, Na 2 O 2 ·2H 2 O, Na 2 O 2 ·2H 2 O 2, and Na 2 O 2 ·8H 2 O. [4] The octahydrate, which is simple to prepare, is white, in ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Diacyl peroxides are typically prepared by treating hydrogen peroxide with acid chlorides or acid anhydrides in the presence of base: [1] H 2 O 2 + 2 RCOCl → (RCO 2) 2 + 2 HCl H 2 O 2 + (RCO) 2 O → (RCO 2) 2 + H 2 O. The reaction competes with hydrolysis of the acylating agent but the hydroperoxide anion is a superior nucleophile relative ...