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Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
A schematic diagram of 4 electrons scattered by 4 magnetic atoms far apart. Each atom is at the center of decaying electron waves. The electrons mediate the interactions among the atoms, whose poles can flip because of the influence of other atoms and the surrounding electrons. Reproduced from [1] and [2].
Schematic representation of two schemes to experimentally realize the Dicke model: on the left, the equilibrium approach based on the dipole coupling between the two levels and, on the right, the nonequilibrium approach based on two-photon processes, namely stimulated Raman scattering. Only the latter scheme is used to realize the Dicke model.
Examples of dipole-dipole and quadrupole-quadrupole exchange interactions in J=1 case. Blue arrow means the transition comes with a phase shift. [21] There are four major mechanisms to induce exchange interactions between two magnetic moments in a system: [20] 1). Direct exchange 2). RKKY 3). Superexchange 4). Spin-Lattice.
In nuclear chemistry and nuclear physics, J-couplings (also called spin-spin coupling or indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. [ 1 ]
For non-protonated carbon atoms the NOE enhancement is small while for carbons that relax by relaxation mechanisms by other than dipole-dipole interactions the NOE enhancement can be significantly reduced. This is one motivation for using deuteriated solvents (e.g. CDCl 3) in 13 C NMR. Since deuterium relaxes by the quadrupolar mechanism, there ...
The final term, often known as the Fermi contact term relates to the direct interaction of the nuclear dipole with the spin dipoles and is only non-zero for states with a finite electron spin density at the position of the nucleus (those with unpaired electrons in s-subshells). It has been argued that one may get a different expression when ...
For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H- 15 N or 1 H- 13 C dipolar couplings are <5 Hz. [ 19 ]