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Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite.It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
There are 28 known radioisotopes and 8 nuclear isomers, the most stable of which are 60 Fe (half-life 2.6 million years) and 55 Fe (half-life 2.7 years). Much of the past work on measuring the isotopic composition of iron has centered on determining 60 Fe variations due to processes accompanying nucleosynthesis (i.e., meteorite studies) and ore ...
The nuclide 54 Fe theoretically can undergo double electron capture to 54 Cr, but the process has never been observed and only a lower limit on the half-life of 4.4×10 20 years has been established. [22] 60 Fe is an extinct radionuclide of long half-life (2.6 million years). [23]
Thus ferrocyanide ([Fe(CN) 6] 4− has no unpaired electrons, meaning it is a low-spin complex. With so-called "weak field ligands" such as water, four of the six electrons are unpaired, meaning it is a high-spin complex. Thus aquo complex [Fe(H 2 O) 6] 2+ is paramagnetic. With chloride, iron(II) forms tetrahedral complexes, e.g. [FeCl 4] 2− ...
The iron cycle is an important component of the terrestrial ecosystems. The ferrous form of iron, Fe 2+, is dominant in the Earth's mantle, core, or deep crust. The ferric form, Fe 3+, is more stable in the presence of oxygen gas. [22] Dust is a key component in the Earth's iron cycle.
These various forms can coexist in equilibrium. [7] At physiological pH, ferric citrate forms an insoluble red polymer. In other conditions, it forms anionic complexes like [FeC 6 H 4 O 7] 2 (H 2 O) 2] 2−. In the present of excess citrate anions, the iron forms negatively charged complexes like [Fe (C 6 H 4 O 7) 2] 5− and [Fe 9 O (C 6 H 4 O ...
Iron(II) acetate describes compounds with formula Fe(CH 3 CO 2) 2 ·(H 2 O) x where x can be 0 (anhydrous) or 4 (tetrahydrate). The anhydrous compound is a white solid, although impure samples can be slightly colored. [ 1 ]
Fe(acac) 3 is an octahedral complex with six equivalent Fe-O bonds with bond distances of about 2.00 Å. The regular geometry is consistent with a high-spin Fe 3+ core with sp3d2 hybridization. As the metal orbitals are all evenly occupied the complex is not subject to Jahn-Teller distortions and thus adopts a D 3 molecular symmetry .