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In thermodynamics, the ebullioscopic constant K b relates molality b to boiling point elevation. [1] It is the ratio of the latter to the former: = i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved.
A kip is a US customary unit of force. It equals 1000 pounds-force , and is used primarily by structural engineers to indicate forces where the value represented in pound-force is inefficient. Although uncommon, it is occasionally also considered a unit of mass , equal to 1000 pounds (i.e. one half of a short ton ).
In physics, natural unit systems are measurement systems for which selected physical constants have been set to 1 through nondimensionalization of physical units.For example, the speed of light c may be set to 1, and it may then be omitted, equating mass and energy directly E = m rather than using c as a conversion factor in the typical mass–energy equivalence equation E = mc 2.
The GF method, sometimes referred to as FG method, is a classical mechanical method introduced by Edgar Bright Wilson to obtain certain internal coordinates for a vibrating semi-rigid molecule, the so-called normal coordinates Q k.
The general form of the Eyring–Polanyi equation somewhat resembles the Arrhenius equation: = ‡ where is the rate constant, ‡ is the Gibbs energy of activation, is the transmission coefficient, is the Boltzmann constant, is the temperature, and is the Planck constant.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
In chemistry, ion transport number, also called the transference number, is the fraction of the total electric current carried in an electrolyte by a given ionic species i: [1] = Differences in transport number arise from differences in electrical mobility.
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...