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Laboratory routes to the solvent-free materials are numerous. A well documented route involves the thermal decomposition of diazonium salts of [BF 4] −: [11] [PhN 2] + [BF 4] − → PhF + BF 3 + N 2. It forms by treatment of a mixture boron trioxide and sodium tetrafluoroborate with sulfuric acid: [12] 6 Na[BF 4] + B 2 O 3 + 6 H 2 SO 4 → 8 ...
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Pure H[BF 4] has not been described. The same holds true for the superacids that are known by the simplified formulas H[PF 6] and H[SbF 6]. [4] [5] However, a solution of BF 3 in HF is highly acidic, having an approximate speciation of [H 2 F] + [BF 4] − (fluoronium tetrafluoroborate) and a Hammett acidity function of −16.6 at 7 mol % BF 3, easily qualifying as a superacid. [6]
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Upload file; Search. Search. Appearance. ... Download as PDF; Printable version ... Appearance. move to sidebar hide. BF3 may refer to: Boron trifluoride, a chemical ...
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Borane–tetrahydrofuran is an adduct derived from borane and tetrahydrofuran (THF). These solutions, which are colorless, are used for reductions and hydroboration, reactions that are useful in synthesis of organic compounds.