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Jablonski diagram including vibrational levels for absorbance, non-radiative decay, and fluorescence. When a molecule absorbs a photon, the photon energy is converted and increases the molecule's internal energy level. Likewise, when an excited molecule releases energy, it can do so in the form of a photon.
English: Jablonski diagram of absorbance, non-radiative decay, and fluorescence. Electronic transitions are about 1 eV. Vibrational transitions are about 0.1 eV. Rotational transitions (not shown) are about 0.001 eV. Absorption is about 1 femtosecond, relaxation takes about 1 picosecond, fluorescence takes about 1 nanosecond.
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A Jablonski diagram describing the mechanism of triplet-triplet annihilation. The energy of the first triplet excited state (T 1) is transferred to a second triplet excited state (T 1), resulting in (1) the first T 1 returning to the singlet ground state S0 and (2) the second T 1 promoting to the singlet excited state (S 1).
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