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The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate , which cyclopropanates an aromatic ring.
It is commonly thought to be named after the Nobel Laureate Eduard Buchner (without umlaut), but it is actually named after the industrial chemist Ernst Büchner. [2] A Büchner funnel fitted with Sintered Disc made of Boro 3.3 Glass. Diagram of filtration set-up using a Büchner flask
Diagram of the vacuum filtration apparatus. By flowing through the aspirator, water will suck out the air contained in the vacuum flask and the Büchner flask.There is therefore a difference in pressure between the exterior and the interior of the flasks : the contents of the Büchner funnel are sucked towards the vacuum flask.
A funnel (E) contains a sample of soil or leaf litter (D), and a heat source (F), in this case an electric lamp (G), heats the sample. Animals escaping from the desiccation of the sample descend through a filter (C) into a preservative liquid (A) in a receptacle (B).
cylindrical type graduated and ungraduated with cone and socket; with pressure equalizing tube; pear shaped, graduated and ungraduated; Pressure-equalizing dropping funnels have an additional narrow-bore glass tube from the bulb of the funnel, to the ground glass joint around the stem.
Eduard Buchner (German: [ˈeːduaʁt ˈbuːxnɐ] ⓘ; 20 May 1860 – 13 August 1917) was a German chemist and zymologist, awarded the 1907 Nobel Prize in Chemistry for his work on fermentation. [ 1 ]
Büchner flask A Büchner funnel is attached to the flask via a black elastomer adapter. The hose barb is connected via vacuum hose to a vacuum source such as an aspirator. ...
His father was the pharmacist, chemist, industrialist and politician Wilhelm Büchner.Ernst was also the nephew of the playwright Georg Büchner and the philosopher, physiologist and physician Ludwig Büchner.