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In molecular physics and chemistry, the van der Waals force (sometimes van de Waals' force) is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; [2] they are comparatively weak and therefore more susceptible to disturbance.
London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds[1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically symmetric; that is, the electrons are ...
An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions. Intermolecular forces are weak relative to intramolecular forces – the forces which ...
In condensed matter physics and physical chemistry, the Lifshitz theory of van der Waals forces, sometimes called the macroscopic theory of van der Waals forces, is a method proposed by Evgeny Mikhailovich Lifshitz in 1954 for treating van der Waals forces between bodies which does not assume pairwise additivity of the individual intermolecular forces; that is to say, the theory takes into ...
The Van der Waals forces are effective only up to several hundred angstroms. When the interactions are too far apart, the dispersion potential decays faster than 1 / r 6 ; {\displaystyle 1/r^{6};} this is called the retarded regime, and the result is a Casimir–Polder force .
Non-covalent interactions can be classified into different categories, such as electrostatic, π-effects, van der Waals forces, and hydrophobic effects. [3] [2] Non-covalent interactions [4] are critical in maintaining the three-dimensional structure of large molecules, such as proteins and nucleic acids.
DLVO theory is a theory of colloidal dispersion stability in which zeta potential is used to explain that as two particles approach one another their ionic atmospheres begin to overlap and a repulsion force is developed. [1] In this theory, two forces are considered to impact on colloidal stability: Van der Waals forces and electrical double ...
For atoms and nonpolar molecules, the London dispersion force is the only intermolecular force, and is responsible for their existence in liquid and solid states. For polar molecules, this force is one part of the van der Waals force, along with forces between the permanent molecular dipole moments.