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A turning point of a differentiable function is a point at which the derivative has an isolated zero and changes sign at the point. [2] A turning point may be either a relative maximum or a relative minimum (also known as local minimum and maximum). A turning point is thus a stationary point, but not all stationary points are turning points.
Potential energy surfaces are commonly shown as three-dimensional graphs, but they can also be represented by two-dimensional graphs, in which the advancement of the reaction is plotted by the use of isoenergetic lines. The collinear system H + H 2 is a simple reaction that allows a two-dimension PES to be plotted in an easy and understandable way.
The x-coordinates of the red circles are stationary points; the blue squares are inflection points. In mathematics, a critical point is the argument of a function where the function derivative is zero (or undefined, as specified below). The value of the function at a critical point is a critical value. [1]
Fermat's theorem gives only a necessary condition for extreme function values, as some stationary points are inflection points (not a maximum or minimum). The function's second derivative , if it exists, can sometimes be used to determine whether a stationary point is a maximum or minimum.
This makes the action an input to the powerful stationary-action principle for classical and for quantum mechanics. Newton's equations of motion for the ball can be derived from the action using the stationary-action principle, but the advantages of action-based mechanics only begin to appear in cases where Newton's laws are difficult to apply.
A stationary point of inflection is not a local extremum. More generally, in the context of functions of several real variables, a stationary point that is not a local extremum is called a saddle point. An example of a stationary point of inflection is the point (0, 0) on the graph of y = x 3. The tangent is the x-axis, which cuts the graph at ...
A system moving between two points takes one particular path; other similar paths are not taken. Each path corresponds to a value of the action. An action principle predicts or explains that the particular path taken has a stationary value for the system's action: similar paths near the one taken have very similar action value.
This involves formulating discrete operators on graphs which are analogous to differential operators in calculus, such as graph Laplacians (or discrete Laplace operators) as discrete versions of the Laplacian, and using these operators to formulate differential equations, difference equations, or variational models on graphs which can be ...