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Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate [9]), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO 3. It is a salt composed of a sodium cation (Na +) and a bicarbonate anion (HCO 3 −). Sodium bicarbonate is a white solid that is crystalline but often appears as a
A bicarbonate salt forms when a positively charged ion attaches to the negatively charged oxygen atoms of the ion, forming an ionic compound. Many bicarbonates are soluble in water at standard temperature and pressure; in particular, sodium bicarbonate contributes to total dissolved solids, a common parameter for assessing water quality. [6]
The most important sodium compounds are table salt (NaCl), soda ash (Na 2 CO 3), baking soda (NaHCO 3), caustic soda (NaOH), sodium nitrate (NaNO 3), di- and tri-sodium phosphates, sodium thiosulfate (Na 2 S 2 O 3 ·5H 2 O), and borax (Na 2 B 4 O 7 ·10H 2 O). [7] In compounds, sodium is usually ionically bonded to water and anions and is ...
The water molecule is amphoteric in aqueous solution. It can either gain a proton to form a hydronium ion H 3 O +, or else lose a proton to form a hydroxide ion OH −. [5] Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base.
One idea is to react carbon dioxide, produced perhaps by the combustion of coal, to form solid carbonates (such as sodium bicarbonate) that could be permanently stored, thus avoiding carbon dioxide emission into the atmosphere. [20] [21] The Solvay process could be modified to give the overall reaction: 2 NaCl + CaCO 3 + CO 2 + H 2 O → 2NaHCO ...
One common form of polar interaction is the hydrogen bond, which is also known as the H-bond. For example, water forms H-bonds and has a molar mass M = 18 and a boiling point of +100 °C, compared to nonpolar methane with M = 16 and a boiling point of –161 °C.
In more acid conditions, aqueous carbon dioxide, CO 2 (aq), is the main form, which, with water, H 2 O, is in equilibrium with carbonic acid – the equilibrium lies strongly towards carbon dioxide. Thus sodium carbonate is basic, sodium bicarbonate is weakly basic, while carbon dioxide itself is a weak acid.
In even a slight presence of water, carbonic acid dehydrates to carbon dioxide and water, which then catalyzes further decomposition. [6] For this reason, carbon dioxide can be considered the carbonic acid anhydride. The hydration equilibrium constant at 25 °C is [H 2 CO 3]/[CO 2] ≈ 1.7×10 −3 in pure water [12] and ≈ 1.2×10 −3 in ...