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The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.
This tendency is called the octet rule, because each bonded atom has 8 valence electrons including shared electrons. Similarly, a transition metal tends to react to form a d 10 s 2 p 6 electron configuration. This tendency is called the 18-electron rule, because each bonded atom has 18 valence electrons including shared electrons.
The valence is the combining capacity of an atom of a given element, determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1.
The valence electrons (here 3s 2 3p 3) are written explicitly for all atoms. Electron configurations of elements beyond hassium (element 108) have never been measured; predictions are used below. As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule.
This is a list of chemical elements and their atomic properties, ordered by atomic number (Z).. Since valence electrons are not clearly defined for the d-block and f-block elements, there not being a clear point at which further ionisation becomes unprofitable, a purely formal definition as number of electrons in the outermost shell has been used.
It now has 8 total valence electrons, which obeys the octet rule. CH 4, for the central C; neutral counting: C contributes 4 electrons, each H radical contributes one each: 4 + 4 × 1 = 8 valence electrons ionic counting: C 4− contributes 8 electrons, each proton contributes 0 each: 8 + 4 × 0 = 8 electrons. Similar for H:
Fe has 8 valence electrons. Each carbonyl group is a net 2 electron donor after the internal σ- and π-bonding are taken into account making 14 electrons. 3 pairs are considered to be involved in Fe–CO σ-bonding and 3 pairs are involved in π-backbonding from Fe to CO reducing the 14 to 2.
Lithium has two electrons in the 1s-subshell and one in the (higher-energy) 2s-subshell, so its configuration is written 1s 2 2s 1 (pronounced "one-s-two, two-s-one"). Phosphorus (atomic number 15) is as follows: 1s 2 2s 2 2p 6 3s 2 3p 3. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used.