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In atomic physics and quantum chemistry, the Aufbau principle (/ ˈ aʊ f b aʊ /, from German: Aufbauprinzip, lit. 'building-up principle'), also called the Aufbau rule, states that in the ground state of an atom or ion, electrons first fill subshells of the lowest available energy, then fill subshells of higher energy.
In a May 1911 paper, [7] Rutherford presented his own physical model for subatomic structure, as an interpretation for the unexpected experimental results. [2] In it, the atom is made up of a central charge (this is the modern atomic nucleus, though Rutherford did not use the term "nucleus" in his paper). Rutherford only committed himself to a ...
Inclusion of extra properties: Traditional periodic tables typically focus on a few key properties, such as atomic number and atomic weight. However, periodic tables of three or more dimensions have the potential to include additional properties, such as electronegativity, ionization energy, electron affinity, or physical properties like ...
The atomic nucleus is a quantum n-body system. The internal motion of nucleons within the nucleus is non-relativistic, and their behavior is governed by the Schrödinger equation. Nucleons are considered to be pointlike, without any internal structure.
The prevailing model of atomic structure before Rutherford's experiments was devised by J. J. Thomson. [2]: 123 Thomson had discovered the electron through his work on cathode rays [3] and proposed that they existed within atoms, and an electric current is electrons hopping from one atom to an adjacent one in a series.
Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids).