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In secondary (2°) haloalkanes, the carbon that carries the halogen atom has two C–C bonds. In tertiary (3°) haloalkanes, the carbon that carries the halogen atom has three C–C bonds. [citation needed] Haloalkanes can also be classified according to the type of halogen on group 17 responding to a specific halogenoalkane.
Halocarbon compounds are chemical compounds in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine – group 17) resulting in the formation of organofluorine compounds, organochlorine compounds, organobromine compounds, and organoiodine compounds.
Haloalkanes are diverse in their properties, making generalizations difficult. Few are acutely toxic, but many pose risks from prolonged exposure. Some problematic aspects include carcinogenicity and liver damage (e.g., carbon tetrachloride). Under certain combustion conditions, chloromethanes convert to phosgene, which is highly toxic.
Lithium–halogen exchange is frequently used to prepare vinyl-, aryl- and primary alkyllithium reagents. Vinyl halides usually undergo lithium–halogen exchange with retention of the stereochemistry of the double bond. [2] The presence of alkoxyl or related chelating groups accelerates lithium–halogen exchange. [3]
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Haloalkane, or halogenoalkane, a group of chemical compounds consisting of alkanes with linked halogens (in particular, bromine-containing haloalkanes) Halomethane compounds: Halon 10001 (iodomethane) Halon 1001 (bromomethane) Halon 1011 (bromochloromethane, CH 2 BrCl) Halon 104 (carbon tetrachloride) Halon 1103 (tribromofluoromethane)
In enzymology, a haloalkane dehalogenase (EC 3.8.1.5) is an enzyme that catalyzes the chemical reaction. 1-haloalkane + H 2 O a primary alcohol + halide. Thus, the two substrates of this enzyme are 1-haloalkane and H 2 O, whereas its two products are primary alcohol and halide.
A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...