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Acrylic acid (IUPAC: prop-2-enoic acid) is an organic compound with the formula CH 2 =CHCOOH. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a characteristic acrid or tart smell. It is miscible with water, alcohols, ethers, and chloroform ...
Acryloyl chloride, like volatile acid chlorides, is a skin irritant, with pulmonary edema in more severe exposures. [6] Other signs and symptoms of acute exposure may include headache, dizziness, and weakness. Gastrointestinal effects may include nausea, vomiting, diarrhea, and stomach ulceration. [7]
2-Ethylhexyl acrylate polymerizes easily. The polymerization can be initiated by light, peroxides, heat, or contaminants.It can react violently when combined with strong oxidants and can form explosive mixtures with air at temperatures above 82 °C (180 °F). [2]
Ethyl acrylate is produced by acid-catalysed esterification of acrylic acid, which in turn is produced by oxidation of propylene. It may also be prepared from acetylene, carbon monoxide and ethanol by a Reppe reaction. Commercial preparations contain a polymerization inhibitor such as hydroquinone, phenothiazine, or hydroquinone ethyl ether. [5]
Butyl acrylate is of low acute toxicity with an LD 50 (rat) of 3143 mg/kg. [4]In rodent models, butyl acrylate is metabolized by carboxylesterase or reactions with glutathione; this detoxification produces acrylic acid, butanol, and mercapturic acid waste, which are excreted.
Another method tested in a study to produce sodium polyacrylate as an alternative to current methods began with Butyl acrylate-acrylic acid copolymer and poly (butyl acrylate). [4] They were synthesized via suspension polymerization by using butyl acrylate as the main monomer and acrylic acid as a secondary monomer. Suspension polymerization ...