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More broadly, the idea of green chemistry can easily be linked (or confused) with related concepts like green engineering, environmental design, or sustainability in general. Green chemistry's complexity and multifaceted nature makes it difficult to devise clear and simple metrics. As a result, "what is green" is often open to debate. [44]
Derivatization is a technique used in chemistry which converts a chemical compound into a product (the reaction's derivate) of similar chemical structure, called a derivative. Generally, a specific functional group of the compound participates in the derivatization reaction and transforms the educt to a derivate of deviating reactivity ...
Some examples of functionality reduced by SmI 2 are provided below. The reactivity of SmI 2 is significantly affected by the choice of solvent. The use of hexamethylphosphoramide (HMPA) as a co-solvent in samarium(II) iodide reductions allows the reaction to be carried out under much milder conditions than in its absence. [ 6 ]
It is a common method to make amines and is widely used in green chemistry since it can be done catalytically in one-pot under mild conditions. In biochemistry, dehydrogenase enzymes use reductive amination to produce the amino acid glutamate. Additionally, there is ongoing research on alternative synthesis mechanisms with various metal ...
Green solvents are environmentally friendly chemical solvents that are used as a part of green chemistry. They came to prominence in 2015, when the UN defined a new sustainability -focused development plan based on 17 sustainable development goals, recognizing the need for green chemistry and green solvents for a more sustainable future. [ 1 ]
Clemmensen reduction is a chemical reaction described as a reduction of ketones or aldehydes to alkanes using zinc amalgam and concentrated hydrochloric acid (HCl). [1] [2] This reaction is named after Erik Christian Clemmensen, a Danish-American chemist.
The word GREEN in the name Green Nanotechnology has dual meaning. On one hand it describes the environment friendly technologies utilized to synthesize particles in nano scale; on the other hand it refers to the nanoparticles synthesis mediated by extracts of chlorophyllus plants. [ 1 ]
The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be reduced. Alkyl and aryl nitro compounds behave differently.