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  2. Quantum number - Wikipedia

    en.wikipedia.org/wiki/Quantum_number

    A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...

  3. Principal quantum number - Wikipedia

    en.wikipedia.org/wiki/Principal_quantum_number

    The four quantum numbers n, ℓ, m, and s specify the complete and unique quantum state of a single electron in an atom, called its wave function or orbital. Two electrons belonging to the same atom cannot have the same values for all four quantum numbers, due to the Pauli exclusion principle .

  4. Electron - Wikipedia

    en.wikipedia.org/wiki/Electron

    In quantum mechanics, the behavior of an electron in an atom is described by an orbital, which is a probability distribution rather than an orbit. In the figure, the shading indicates the relative probability to "find" the electron, having the energy corresponding to the given quantum numbers, at that point.

  5. Total angular momentum quantum number - Wikipedia

    en.wikipedia.org/wiki/Total_angular_momentum...

    The associated quantum number is the main total angular momentum quantum number j. It can take the following range of values, jumping only in integer steps: [ 1 ] | ℓ − s | ≤ j ≤ ℓ + s {\displaystyle \vert \ell -s\vert \leq j\leq \ell +s} where ℓ is the azimuthal quantum number (parameterizing the orbital angular momentum) and s is ...

  6. Energy level - Wikipedia

    en.wikipedia.org/wiki/Energy_level

    This equation is obtained from combining the Rydberg formula for any hydrogen-like element (shown below) with E = hν = hc / λ assuming that the principal quantum number n above = n 1 in the Rydberg formula and n 2 = ∞ (principal quantum number of the energy level the electron descends from, when emitting a photon).

  7. Term symbol - Wikipedia

    en.wikipedia.org/wiki/Term_symbol

    Quantities with a subscript 1 are for the parent ion, n and ℓ are principal and orbital quantum numbers for the excited electron, K and J are quantum numbers for = + and = + where and are orbital angular momentum and spin for the excited electron respectively. “o” represents a parity of excited atom.

  8. Slater's rules - Wikipedia

    en.wikipedia.org/wiki/Slater's_rules

    An amount of 0.35 from each other electron within the same group except for the [1s] group, where the other electron contributes only 0.30. If the group is of the [ns, np] type, an amount of 0.85 from each electron with principal quantum number (n–1), and an amount of 1.00 for each electron with principal quantum number (n–2) or less.

  9. Azimuthal quantum number - Wikipedia

    en.wikipedia.org/wiki/Azimuthal_quantum_number

    The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment