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The one-phase Stefan problem is based on an assumption that one of the material phases may be neglected. Typically this is achieved by assuming that a phase is at the phase change temperature and hence any variation from this leads to a change of phase.
In thermodynamics, a temperature–entropy (T–s) diagram is a thermodynamic diagram used to visualize changes to temperature (T ) and specific entropy (s) during a thermodynamic process or cycle as the graph of a curve. It is a useful and common tool, particularly because it helps to visualize the heat transfer during a process.
Phase transition or phase change, takes place in a thermodynamic system from one phase or state of matter to another one by heat transfer. Phase change examples are the melting of ice or the boiling of water. The Mason equation explains the growth of a water droplet based on the effects of heat transport on evaporation and condensation.
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .
TTT diagram of isothermal transformations of a hypoeutectoid carbon steel; showing the main components obtained when cooling the steel and its relation with the Fe-C phase diagram of carbon steels. Austenite is slightly undercooled when quenched below Eutectoid temperature. When given more time, stable microconstituents can form: ferrite and ...
A phase-change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other.
However, if the specific heat changes, the LMTD approach will no longer be accurate. A particular case for the LMTD are condensers and reboilers, where the latent heat associated to phase change is a special case of the hypothesis. For a condenser, the hot fluid inlet temperature is then equivalent to the hot fluid exit temperature.
If different phases of the same pure substance are present in a multiphase system, interphase heat transfer will result in a change of phase, which is always accompanied by interphase mass transfer. The combination of heat transfer with mass transfer during phase change makes multiphase systems distinctly more challenging than simpler systems.