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The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule.It is a better approximation for the vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states.
This is a list of potential energy functions that are frequently used in quantum mechanics and have any meaning. ... Morse potential; Morse/Long-range potential;
The Morse potential has been applied to studies of molecular vibrations and solids, [22] and also inspired the functional form of more accurate potentials such as the bond-order potentials. Ionic materials are often described by a sum of a short-range repulsive term, such as the Buckingham pair potential , and a long-range Coulomb potential ...
The Morse/Long-range potential (MLR potential) is an interatomic interaction model for the potential energy of a diatomic molecule. Due to the simplicity of the regular Morse potential (it only has three adjustable parameters), it is very limited in its applicability in modern spectroscopy .
The Morse potential (blue) and harmonic oscillator potential (green). The potential at infinite internuclear distance is the dissociation energy for pure vibrational spectra. For vibronic spectra there are two potential curves (see Figure at right), and the dissociation limit is the upper state energy at infinite distance.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The notion of a Morse function can be generalized to consider functions that have nondegenerate manifolds of critical points. A Morse–Bott function is a smooth function on a manifold whose critical set is a closed submanifold and whose Hessian is non-degenerate in the normal direction. (Equivalently, the kernel of the Hessian at a critical ...
The first English use of the expression "meaning of life" appears in Thomas Carlyle's Sartor Resartus (1833–1834), book II chapter IX, "The Everlasting Yea". [1]Our Life is compassed round with Necessity; yet is the meaning of Life itself no other than Freedom, than Voluntary Force: thus have we a warfare; in the beginning, especially, a hard-fought battle.