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Aromatization is a chemical reaction in which an aromatic system is formed from a single nonaromatic precursor. Typically aromatization is achieved by dehydrogenation of existing cyclic compounds, illustrated by the conversion of cyclohexane into benzene.
Toluene is also found in cigarette smoke and car exhaust. If not in contact with air, toluene can remain unchanged in soil or water for a long time. [39] Toluene is a common solvent, e.g. for paints, paint thinners, silicone sealants, [40] many chemical reactants, rubber, printing ink, adhesives (glues), lacquers, leather tanners, and ...
Structures of the three isomers of tolyl group. In organic chemistry, tolyl groups are functional groups related to toluene. [1] They have the general formula CH 3 C 6 H 4 −R, the change of the relative position of the methyl and the R substituent on the aromatic ring can generate three possible structural isomers 1,2 (ortho), 1,3 (meta), and 1,4 (para).
Toluene (or methylbenzene) is a common chemical found in chemistry laboratories. An alkylbenzene is a chemical compound that contains a monocyclic aromatic ring attaching to one or more saturated hydrocarbon chains. [ 1 ]
Hydrodealkylation is a chemical reaction that often involves reacting an aromatic hydrocarbon, such as toluene, in the presence of hydrogen gas to form a simpler aromatic hydrocarbon devoid of functional groups. An example is the conversion of 1,2,4-trimethylbenzene to xylene. [1]
Transalkylation of toluene and trimethylbenzene to produce xylene. In this example, the M/R ratio is 2. This type of reaction can also be performed with toluene and trimethylbenzene to produce xylene. The reaction occurs via equilibrium, so the product is not pure xylene. Many products are produced with varying numbers of methyl groups.
A dearomatization reaction is an organic reaction in which the reactants are arenes and the products permanently lose their aromaticity. [1] It is of some importance in synthetic organic chemistry for the organic synthesis of new building blocks [ 1 ] and in total synthesis . [ 2 ]
A ring forming reaction or ring-closing reaction in organic chemistry is an umbrella term for a variety of reactions that introduce one or more rings into a molecule. A heterocycle forming reaction is a reaction that introduces a new heterocycle. [1] [2] Important classes of ring forming reactions include annulations [3] and cycloadditions ...