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The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the ...
Replacing work with a change in volume gives = Since the process is isochoric, dV = 0 , the previous equation now gives d U = d Q {\displaystyle dU=dQ} Using the definition of specific heat capacity at constant volume, c v = ( dQ / dT )/ m , where m is the mass of the gas, we get d Q = m c v d T {\displaystyle dQ=mc_{\mathrm {v} }\,dT}
The terms "intensive and extensive quantities" were introduced into physics by German mathematician Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917. [ 1 ] [ 2 ] According to International Union of Pure and Applied Chemistry (IUPAC), an intensive property or intensive quantity is one whose magnitude is ...
2.4 Statistical physics. ... Free expansion; Reversibility; ... where k B is the Boltzmann constant, and Ω denotes the volume of macrostate in the phase space or ...
Pressure–volume work (or PV or P-V work) occurs when the volume V of a system changes. PV work is often measured in units of litre-atmospheres where 1 L·atm = 101.325 J. However, the litre-atmosphere is not a recognized unit in the SI system of units, which measures P in pascals (Pa), V in m 3, and PV in joules (J), where 1 J = 1 Pa·m 3.
A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
where V 100 is the volume occupied by a given sample of gas at 100 °C; V 0 is the volume occupied by the same sample of gas at 0 °C; and k is a constant which is the same for all gases at constant pressure. This equation does not contain the temperature and so is not what became known as Charles's Law.
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.