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The core −C(=O)−(N) of amides is called the amide group (specifically, carboxamide group). In the usual nomenclature, one adds the term "amide" to the stem of the parent acid's name. For instance, the amide derived from acetic acid is named acetamide (CH 3 CONH 2 ).
The chemical reactions of dimethylacetamide are typical of N,N-disubstituted amides. Hydrolysis of the acyl-N bond occurs in the presence of acids: CH 3 CON(CH 3) 2 + H 2 O + HCl → CH 3 COOH + (CH 3) 2 NH 2 + Cl −. However, it is resistant to bases. For this reason DMA is a useful solvent for reactions involving strong bases such as sodium ...
In enzymology, a N-substituted formamide deformylase (EC 3.5.1.91) is an enzyme that catalyzes the chemical reaction. N-benzylformamide + H 2 O formate + benzylamine. Thus, the two substrates of this enzyme are N-benzylformamide and H 2 O, whereas its two products are formate and benzylamine.
The Beckmann rearrangement, named after the German chemist Ernst Otto Beckmann (1853–1923), is a rearrangement of an oxime functional group to substituted amides. [1] [2] The rearrangement has also been successfully performed on haloimines and nitrones. Cyclic oximes and haloimines yield lactams.
Pyridines are especially reactive when substituted in the aromatic ortho position or aromatic para position because then the negative charge is effectively delocalized at the nitrogen position. One classic reaction is the Chichibabin reaction ( Aleksei Chichibabin , 1914) in which pyridine is reacted with an alkali-metal amide such as sodium ...
Pivalamide (2,2-dimethylpropanamide, or NDEPA), a simple amide substituted with a tert-butyl group having the chemical formula: t Bu-CO-NH 2. It is the amide of pivalic acid. N-Pivalamide, is a functional group having the following chemical formula: tBu-CO-NH-R
The lithium amides are more common and more soluble than the other alkali metal analogs. Potassium amides are prepared by transmetallation of lithium amides with potassium t-butoxide (see also Schlosser base) or by reaction of the amine with potassium, potassium hydride, n-butylpotassium, or benzylpotassium. [2]
It is the amide of propanoic acid. This organic compound is a mono-substituted amide. [2] Organic compounds of the amide group can react in many different organic processes to form other useful compounds for synthesis.