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Methyl ethyl ketone peroxide (MEKP) is an organic peroxide with the formula [(CH 3)(C 2 H 5)C(O 2 H)] 2 O 2. MEKP is a colorless oily liquid. It is widely used in vulcanization (crosslinking) of polymers. [3] It is derived from the reaction of methyl ethyl ketone and hydrogen peroxide under acidic conditions.
Vinyl ester resin is extensively used to manufacture FRP tanks and vessels as per BS4994. For laminating process, vinyl ester is usually initiated with methyl ethyl ketone peroxide. It has greater strength and mechanical properties than polyester and less than epoxy resin. Renewable precursors to vinyl ester resins have been developed. [2]
Thus, organic peroxides are useful as initiators for some types of polymerization, such as the acrylic, unsaturated polyester, and vinyl ester resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can explosively combust.
Since vinyl ester resins must be pre-accelerated with amine accelerator or cobalt, their processing time at room temperature is shorter than with epoxy-based prepregs. Catalysts (also called hardeners) include peroxides such as methyl ethyl ketone peroxide (MEKP), acetyl acetone peroxide (AAP) or cyclohexanone peroxide (CHP).
Figure 3: Simplified chemical reactions associated with curing of a drying oil. In the first step, the diene undergoes autoxidation to give a hydroperoxide. In the second step, the hydroperoxide combines with another unsaturated side chain to generate a crosslink. [4] Epoxy resins are typically cured by the use of additives, often called hardeners.
[5] Benzoxazine resin synthetic pathway, structure and cure mechanism. Cure is characterised by expansion rather than shrinkage and uses include structural prepregs, liquid molding and film adhesives for composite construction, bonding and repair. The high aromatic content of the high molecular weight polymers provides enhanced mechanical and ...
The most common resin system used for the spray-up process is general purpose or DCDP polyester; isophthalic polyesters and vinyl ester resins are also sometimes used. Fast-reacting resins with a pot life of 30 to 40 minutes are typical. The resin often contains a significant amount of filler.
Vinyl ester resin is an example of a synthetic resin. [1] Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, [2] such as acrylates or epoxides.