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The weight percent of vinyl acetate usually varies from 10 to 50%, with the remainder being ethylene. There are three different types of EVA copolymer, which differ in the vinyl acetate (VA) content and the way the materials are used. The EVA copolymer which is based on a low proportion of VA (approximately up to 4%) may be referred to as vinyl ...
Polyvinyl acetate was discovered in Germany in 1912 by Fritz Klatte. [3] The monomer, vinyl acetate, was first produced on an industrial scale by the addition of acetic acid to acetylene with a mercury(I) salt, [4] but it is now primarily made by palladium-catalyzed oxidative addition of acetic acid to ethylene.
[39]: 235 Due to decreasing crystallinity ethylene vinyl acetate copolymers are getting softer with increasing comonomer content. The polar side groups change the chemical properties significantly (compared to polyethylene): [ 19 ] : 224 weather resistance, adhesiveness and weldability rise with comonomer content, while the chemical resistance ...
Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde , the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis.
Acrylic elastomer is a general term for a type of synthetic rubber whose primary component is acrylic acid alkyl ester (ethyl or butyl ester). [3] Acrylic elastomer possesses characteristics of heat and oil resistance, with the ability to withstand temperatures of 170–180 °C.
Vinyl acetate is the acetate ester of vinyl alcohol. Since vinyl alcohol is highly unstable (with respect to acetaldehyde), the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. [6]
Vinyltriethoxysilane and the related vinyltrimethoxysilane are used as monomers and comonomer for polymers such as ethylene-vinyltrimethoxysilane and ethylene-vinyl acetate-vinyltrimethoxysilane. Vinyltrialkoxysilanes are also used as cross-linking agents during the manufacture of cross-linked polyethylene (PEX).
Polyvinyl butyral (or PVB) is a resin mostly used for applications that require strong binding, optical clarity, adhesion to many surfaces, toughness and flexibility. It is prepared from polyvinyl alcohol by reaction with butyraldehyde.