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The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The molar gas constant (also known as the gas constant, universal gas constant, or ideal gas constant) is denoted by the symbol R or R. It is the molar equivalent to the Boltzmann constant , expressed in units of energy per temperature increment per amount of substance , rather than energy per temperature increment per particle .
One langmuir corresponds to an exposure of 10 −6 Torr during one second. [1] [2] For example, exposing a surface to a gas pressure of 10 −8 Torr for 100 seconds corresponds to 1 L. Similarly, keeping the pressure of oxygen gas at 2.5·10 −6 Torr for 40 seconds will give a dose of 100 L.
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The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The table below displays densities and specific volumes for various common substances that may be useful. The values were recorded at standard temperature and pressure, which is defined as air at 0 °C (273.15 K, 32 °F) and 1 atm (101.325 kN/m 2, 101.325 kPa, 14.7 psia, 0 psig, 30 in Hg, 760 torr). [4]
The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa