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Living cationic polymerization is a living polymerization technique involving cationic propagating species. [1] [2] It enables the synthesis of very well defined polymers (low molar mass distribution) and of polymers with unusual architecture such as star polymers and block copolymers and living cationic polymerization is therefore as such of commercial and academic interest.
In polymer chemistry, ionic polymerization is a chain-growth polymerization in which active centers are ions or ion pairs. [2] It can be considered as an alternative to radical polymerization, and may refer to anionic polymerization or cationic polymerization. [3] As with radical polymerization, reactions are initiated by a reactive compound.
Other polymers formed by cationic polymerization are homopolymers and copolymers of polyterpenes, such as pinenes (plant-derived products), that are used as tackifiers. In the field of heterocycles, 1,3,5-trioxane is copolymerized with small amounts of ethylene oxide to form the highly crystalline polyoxymethylene plastic.
Another type of lipid-nanoparticle that can be used for drug delivery to the brain is a cationic liposome. These are lipid molecules that are positively charged. [6] One example of cationic liposomes uses bolaamphiphiles, which contain hydrophilic groups surrounding a hydrophobic chain to strengthen the boundary of the nano-vesicle containing ...
Submission of preprints is accepted by all open access journals. Over the last decade, they have been joined by most subscription journals, however publisher policies are often vague or ill-defined. [1] In general, most publishers that permit preprints require that:
Cationic Acetylcholine binding to a tryptophan residue of the nicotinamide acetylcholine receptor via a cation–π effect. An example of cation–π interactions in molecular recognition is seen in the nicotinic acetylcholine receptor (nAChR) which binds its endogenous ligand , acetylcholine (a positively charged molecule), via a cation–π ...
Thiolated polymers – designated thiomers – are functional polymers used in biotechnology product development with the intention to prolong mucosal drug residence time and to enhance absorption of drugs. The name thiomer was coined by Andreas Bernkop-Schnürch in 2000. [1] Thiomers have thiol bearing side chains.
In the oil and gas industry, polyacrylamide derivatives (especially co-polymers) have a substantial effect on production by enhanced oil recovery by viscosity enhancement. High viscosity aqueous solutions can be generated with low concentrations of polyacrylamide polymers, which are injected to improve the economics of conventional water-flooding.
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