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Pulse electrolysis is an alternate electrolysis method that utilises a pulsed direct current to initiate non-spontaneous chemical reactions. [1] [2] [3] Also known as pulsed direct current (PDC) electrolysis, the increased number of variables that it introduces to the electrolysis method can change the application of the current to the electrodes and the resulting outcome.
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell .
Differential pulse voltammetry: An electrochemical technique similar to normal pulse voltammetry but the applied base potential is increased or decreased steadily, and the pulse height: base height ratio is kept constant. In DPV, measurements of current are taken twice during each drop, first immediately before the pulse and second before the ...
The pulse electroplating or pulse electrodeposition (PED) process involves the swift alternating of the electrical potential or current between two different values, resulting in a series of pulses of equal amplitude, duration, and polarity, separated by zero current. By changing the pulse amplitude and width, it is possible to change the ...
Cathodic stripping voltammetry is a voltammetric method for quantitative determination of specific ionic species. [6] It is similar to the trace analysis method anodic stripping voltammetry, except that for the plating step, the potential is held at an oxidizing potential, and the oxidized species are stripped from the electrode by sweeping the potential negatively.
Double-pulsed chronoamperometry waveform showing integrated region for charge determination.. In electrochemistry, chronoamperometry is an analytical technique in which the electric potential of the working electrode is stepped and the resulting current from faradaic processes occurring at the electrode (caused by the potential step) is monitored as a function of time.
Radiolysis is the dissociation of molecules by ionizing radiation.It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux.The radiation in this context is associated with ionizing radiation; radiolysis is therefore distinguished from, for example, photolysis of the Cl 2 molecule into two Cl-radicals, where (ultraviolet or visible spectrum) light is used.
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the sample's composition.