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Ammonium compounds are used not only for fertilisers, but also explosives. Billingham-on-Tees was a small village in 1917, when its Grange Farm was chosen to be the site of a large chemical works. On 22 March 1918, the Minister of Munitions approved the site to be developed as a factory that would make ammonium nitrate. [1]
As ammonium nitrate is a salt, both the cation, NH + 4, and the anion, NO − 3, may take part in chemical reactions. Solid ammonium nitrate decomposes on heating. At temperatures below around 300 °C, the decomposition mainly produces nitrous oxide and water: NH 4 NO 3 → N 2 O + 2 H 2 O. At higher temperatures, the following reaction ...
Nitrogen cycle. Nitrification is the biological oxidation of ammonia to nitrate via the intermediary nitrite.Nitrification is an important step in the nitrogen cycle in soil.The process of complete nitrification may occur through separate organisms [1] or entirely within one organism, as in comammox bacteria.
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
[12] [13] Complete nitrification, the conversion of ammonia to nitrate in a single step known as comammox, has an energy yield (∆G°′) of −349 kJ mol −1 NH 3, while the energy yields for the ammonia-oxidation and nitrite-oxidation steps of the observed two-step reaction are −275 kJ mol −1 NH 3, and −74 kJ mol −1 NO 2 − ...
Lebanese authorities said 2,750 tonnes of ammonium nitrate had been stored for years at the Beirut port without safety measures. * Ammonium nitrate is an industrial chemical commonly used in ...
Ammonia is considered to be a weak base. It combines with acids to form ammonium salts; thus, with hydrochloric acid it forms ammonium chloride (sal ammoniac); with nitric acid, ammonium nitrate, etc. Perfectly dry ammonia gas will not combine with perfectly dry hydrogen chloride gas; moisture is necessary to bring about the reaction. [38] [39]
The colossal explosion in Lebanon’s capital this week was apparently caused when more than 2,700 tons of ammonium nitrate, a highly volatile chemical, detonated. Ammonium nitrate is commercially ...