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Polychlorotrifluoroethylene (PCTFE or PTFCE) is a thermoplastic chlorofluoropolymer with the molecular formula (CF 2 CClF) n, where n is the number of monomer units in the polymer molecule. It is similar to polytetrafluoroethene (PTFE), except that it is a homopolymer of the monomer chlorotrifluoroethylene (CTFE) instead of tetrafluoroethene.
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. [3] The commonly known brand name of PTFE-based composition is Teflon by Chemours , [ 4 ] a spin-off from DuPont , which originally invented the compound in 1938. [ 4 ]
A fluoropolymer is a fluorocarbon-based polymer with multiple carbon–fluorine bonds. It is characterized by a high resistance to solvents , acids , and bases . The best known fluoropolymer is polytetrafluoroethylene under the brand name "Teflon," trademarked by the DuPont Company.
Chlorotrifluoroethylene (CTFE) is a chlorofluorocarbon with chemical formula CFCl=CF 2.It is commonly used as a refrigerant in cryogenic applications. CTFE has a carbon-carbon double bond and so can be polymerized to form polychlorotrifluoroethylene or copolymerized to produce the plastic ECTFE.
PCTFE (polychlorotrifluoroethylene, structural unit: –CF 2 CFCl–) is another important compound. It differs from PTFE by having a quarter of fluorine replaced with chlorines, yet this difference brings even greater hardness, creep resistance, and moisture persistence. [130]
A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
Pentafluorophenol, a perfluorinated compound.. A perfluorinated compound (PFC) or perfluoro compound is an organofluorine compound that lacks C-H bonds. Many perfluorinated compounds have properties that are quite different from their C-H containing analogues.