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Specific volume is the volume occupied by a unit of mass of a material. [1] In many cases, the specific volume is a useful quantity to determine because, as an intensive property, it can be used to determine the complete state of a system in conjunction with another independent intensive variable. The specific volume also allows systems to be ...
2 volumes of hydrogen + 1 volume of oxygen = 2 volume of gaseous water. could also be expressed as 2 molecules of hydrogen + 1 molecule of oxygen = 2 molecule of water. The law of combining volumes of gases was announced publicly by Joseph Louis Gay-Lussac on the last day of 1808, and published in 1809.
Specific volume is commonly applied to: Molar volume; Volume (thermodynamics) Partial molar volume; Imagine a variable-volume, airtight chamber containing a certain number of atoms of oxygen gas. Consider the following four examples: If the chamber is made smaller without allowing gas in or out, the density increases and the specific volume ...
In thermodynamics, Bridgman's thermodynamic equations are a basic set of thermodynamic equations, derived using a method of generating multiple thermodynamic identities involving a number of thermodynamic quantities.
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
Examples are internal energy, enthalpy, Helmholtz free energy, Gibbs free energy, thermodynamic temperature, and entropy. For a given body, of a given chemical constitution, when its thermodynamic state has been fully defined by its pressure and volume, then its temperature is uniquely determined.
Since the Gibbs free energy is the Legendre transformation of the internal energy, the derivatives can be replaced by their definitions, transforming the above equation into: [4] d G = V d p − S d T + ∑ i = 1 I μ i d N i {\displaystyle \mathrm {d} G=V\mathrm {d} p-S\mathrm {d} T+\sum _{i=1}^{I}\mu _{i}\mathrm {d} N_{i}}
The van der Waals equation of state may be written as (+) =where is the absolute temperature, is the pressure, is the molar volume and is the universal gas constant.Note that = /, where is the volume, and = /, where is the number of moles, is the number of particles, and is the Avogadro constant.