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Examples of the exact sciences are mathematics, optics, astronomy, [3] and physics, which many philosophers from Descartes, Leibniz, and Kant to the logical positivists took as paradigms of rational and objective knowledge. [4] These sciences have been practiced in many cultures from antiquity [5] [6] to modern times.
The exact mass of an isotopic species (more appropriately, the calculated exact mass [9]) is obtained by summing the masses of the individual isotopes of the molecule. For example, the exact mass of water containing two hydrogen-1 ( 1 H) and one oxygen-16 ( 16 O) is 1.0078 + 1.0078 + 15.9949 = 18.0105 Da.
Accuracy is also used as a statistical measure of how well a binary classification test correctly identifies or excludes a condition. That is, the accuracy is the proportion of correct predictions (both true positives and true negatives) among the total number of cases examined. [10]
An assay (analysis) is never an isolated process, as it must be accompanied with pre- and post-analytic procedures. Both the communication order (the request to perform an assay plus related information) and the handling of the specimen itself (the collecting, documenting, transporting, and processing done before beginning the assay) are pre-analytic steps.
In analytical chemistry, quantitative analysis is the determination of the absolute or relative abundance (often expressed as a concentration) of one, several or all particular substance(s) present in a sample. [1] It relates to the determination of percentage of constituents in any given sample. [2]
The uncertainty in molecular mass reflects variance (error) in measurement not the natural variance in isotopic abundances across the globe. In high-resolution mass spectrometry the mass isotopomers 12 C 1 H 4 and 13 C 1 H 4 are observed as distinct molecules, with molecular masses of approximately 16.031 Da and 17.035 Da, respectively.
Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. [1] [2] In other words, measurement is a process of determining how large or small a physical quantity is as compared to a basic reference quantity of the same kind. [3]
In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration.Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1]