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  2. pH - Wikipedia

    en.wikipedia.org/wiki/PH

    For alkaline solutions, an additional term is added to the mass-balance equation for hydrogen. Since the addition of hydroxide reduces the hydrogen ion concentration, and the hydroxide ion concentration is constrained by the self-ionization equilibrium to be equal to K w [ H + ] {\displaystyle {\frac {K_{w}}{{\ce {[H+]}}}}} , the resulting ...

  3. Isohydric principle - Wikipedia

    en.wikipedia.org/wiki/Isohydric_principle

    The isohydric principle is the phenomenon whereby multiple acid/base pairs in solution will be in equilibrium with one another, tied together by their common reagent: the hydrogen ion and hence, the pH of solution. That is, when several buffers are present together in the same solution, they are all exposed to the same hydrogen ion activity.

  4. Acidity function - Wikipedia

    en.wikipedia.org/wiki/Acidity_function

    In this case H 0 and H − are equivalent to pH values determined by the buffer equation or Henderson-Hasselbalch equation. However, an H 0 value of −21 (a 25% solution of SbF 5 in HSO 3 F) [5] does not imply a hydrogen ion concentration of 10 21 mol/dm 3: such a "solution" would have a density more than a hundred times greater than a neutron ...

  5. Charlot equation - Wikipedia

    en.wikipedia.org/wiki/Charlot_equation

    The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation ...

  6. Hydrogen ion - Wikipedia

    en.wikipedia.org/wiki/Hydrogen_ion

    The concentration of hydrogen ions and pH are inversely proportional; in an aqueous solution, an increased concentration of hydrogen ions yields a low pH, and subsequently, an acidic product. By definition, an acid is an ion or molecule that can donate a proton, and when introduced to a solution it will react with water molecules (H 2 O) to ...

  7. RICE chart - Wikipedia

    en.wikipedia.org/wiki/RICE_chart

    With specific values for C a and K a this quadratic equation can be solved for x. Assuming [4] that pH = −log 10 [H +] the pH can be calculated as pH = −log 10 x. If the degree of dissociation is quite small, C a ≫ x and the expression simplifies to = and pH = ⁠ 1 / 2 ⁠ (pK a − log C a).

  8. Aqueous solution - Wikipedia

    en.wikipedia.org/wiki/Aqueous_solution

    In an aqueous solution the hydrogen ions (H +) and hydroxide ions (OH −) are in Arrhenius balance ([H +] [OH −] = K w = 1 x 10 −14 at 298 K). Acids and bases are aqueous solutions, as part of their Arrhenius definitions. [1] An example of an Arrhenius acid is hydrogen chloride (HCl) because of its dissociation of the hydrogen ion when ...

  9. Equilibrium constant - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_constant

    pH is defined in terms of the activity of the hydrogen ion pH = −log 10 {H + } In the approximation of ideal behaviour, activity is replaced by concentration. pH is measured by means of a glass electrode, a mixed equilibrium constant, also known as a Brønsted constant, may result.