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Linear alkylbenzenes (sometimes also known as LABs) are a family of organic compounds with the formula C 6 H 5 C n H 2n+1. Typically, n lies between 10 and 16, although generally supplied as a tighter cut, such as C 12 -C 15 , C 12 -C 13 and C 10 -C 13 , for detergent use. [ 1 ]
In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process:
Preparation. 1,3,5-Triethylbenzene can be prepared by a Friedel-Crafts alkylation of benzene with ethyl bromide in presence of aluminium chloride. [4] Properties
Nitrobenzene is prepared by nitration of benzene with a mixture of concentrated sulfuric acid, water, and nitric acid. This mixture is sometimes called "mixed acid." The production of nitrobenzene is one of the most dangerous processes conducted in the chemical industry because of the exothermicity of the reaction (ΔH = −117 kJ/mol). [5] +
The benzilic acid rearrangement is formally the 1,2-rearrangement of 1,2-diketones to form α-hydroxy–carboxylic acids using a base.This reaction receives its name from the reaction of benzil with potassium hydroxide to form benzilic acid.
Benzidine is prepared in a two step process from nitrobenzene.First, the nitrobenzene is converted to 1,2-diphenylhydrazine, usually using iron powder as the reducing agent.
Xylene is used in the laboratory to make baths with dry ice to cool reaction vessels, [17] and as a solvent to remove synthetic immersion oil from the microscope objective in light microscopy. [18] In histology, xylene is the most widely used clearing agent. [19] Xylene is used to remove paraffin from dried microscope slides prior to staining.
The other principal route is by the oxidative dehydrogenation of benzene: 2 C 6 H 6 + ½ O 2 → C 6 H 5 −C 6 H 5 + H 2 O. Annually 40,000,000 kg are produced by these routes. [13] In the laboratory, biphenyl can also be synthesized by treating phenylmagnesium bromide with copper(II) salts. It can also be prepared using diazonium salts.