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In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1][2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.
Free-radical addition. In organic chemistry, free-radical addition is an addition reaction which involves free radicals. Radical additions are known for a variety of unsaturated substrates, both olefinic or aromatic and with or without heteroatoms. Free-radical reactions depend on one or more relatively weak bonds in a reagent.
The formula of alkyl radicals are the same as alkyl groups, except the free valence "−" is replaced by the dot "•" and adding "radical" to the name of the alkyl group (e.g. methyl radical •CH 3). The naming convention is taken from IUPAC nomenclature:
The chemical basis for Markovnikov's Rule is the formation of the most stable carbocation during the addition process. The addition of the hydrogen ion to one carbon atom in the alkene creates a positive charge on the other carbon, forming a carbocation intermediate. The more substituted the carbocation, the more stable it is, due to induction ...
e. In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical building blocks (repeat units). Free radicals can be formed by a number of different mechanisms, usually involving separate initiator molecules.
Nested radical. In algebra, a nested radical is a radical expression (one containing a square root sign, cube root sign, etc.) that contains (nests) another radical expression. Examples include. which arises in discussing the regular pentagon, and more complicated ones such as.
n. th root. In mathematics, an nth root of a number x is a number r (the root) which, when raised to the power of the positive integer n, yields x: The integer n is called the index or degree, and the number x of which the root is taken is the radicand. A root of degree 2 is called a square root and a root of degree 3, a cube root.
In chemistry, the amino radical, ·NH2, also known as the aminyl or azanyl, is the neutral form of the amide ion (NH− 2). Aminyl radicals are highly reactive and consequently short-lived, like most radicals; however, they form an important part of nitrogen chemistry. In sufficiently high concentration, amino radicals dimerise to form hydrazine.