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  2. Metal ions in aqueous solution - Wikipedia

    en.wikipedia.org/wiki/Metal_ions_in_aqueous_solution

    Solvent exchange is generally slower for trivalent than for divalent ions, as the higher electrical charge on the cation makes for stronger M-OH 2 bonds and, in consequence, higher activation energy for the dissociative reaction step, [M(H 2 O) n] 3+ → [M(H 2 O) n-1] 3+ + H 2 O. The values in the table show that this is due to both activation ...

  3. Metal aquo complex - Wikipedia

    en.wikipedia.org/wiki/Metal_aquo_complex

    Rates vary over many orders of magnitude. The main factor affecting rates is charge: highly charged metal aquo cations exchange their water more slowly than singly charged cations. Thus, the exchange rates for [Na(H 2 O) 6] + and [Al(H 2 O) 6] 3+ differ by a factor of 10 9. Electron configuration is also a major factor, illustrated by the fact ...

  4. Ion exchange - Wikipedia

    en.wikipedia.org/wiki/Ion_exchange

    There are also amphoteric exchangers that are able to exchange both cations and anions simultaneously. However, the simultaneous exchange of cations and anions is often performed in mixed beds, which contain a mixture of anion- and cation-exchange resins, or passing the solution through several different ion-exchange materials. Ion exchanger.

  5. Cation-exchange capacity - Wikipedia

    en.wikipedia.org/wiki/Cation-exchange_capacity

    Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. [1] Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. [ 2 ]

  6. Aqueous solution - Wikipedia

    en.wikipedia.org/wiki/Aqueous_solution

    Metathesis reactions are another term for double-displacement; that is, when a cation displaces to form an ionic bond with the other anion. The cation bonded with the latter anion will dissociate and bond with the other anion. [1] A common metathesis reaction in aqueous solutions is a precipitation reaction.

  7. Pitzer equations - Wikipedia

    en.wikipedia.org/wiki/Pitzer_equations

    Pitzer equations [1] are important for the understanding of the behaviour of ions dissolved in natural waters such as rivers, lakes and sea-water. [ 2 ] [ 3 ] [ 4 ] They were first described by physical chemist Kenneth Pitzer . [ 5 ]

  8. Single displacement reaction - Wikipedia

    en.wikipedia.org/wiki/Single_displacement_reaction

    A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by an atom or group. [1] [2] [3] It can be represented generically as: + +

  9. Self-ionization of water - Wikipedia

    en.wikipedia.org/wiki/Self-ionization_of_water

    The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.