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In short, alkyl groups tend to give electrons, leading to the induction effect. However, such an effect has been questioned. [2] As the induced change in polarity is less than the original polarity, the inductive effect rapidly dies out and is significant only over a short distance. Moreover, the inductive effect is permanent but feeble since ...
In theoretical chemistry, molecular electronic transitions take place when electrons in a molecule are excited from one energy level to a higher energy level. The energy change associated with this transition provides information on the structure of the molecule and determines many of its properties, such as colour.
Furthermore, theories have been put forward to take into account the effects of vibronic coupling on electron transfer, in particular, the PKS theory of electron transfer. [10] In proteins, ET rates are governed by the bond structures: the electrons, in effect, tunnel through the bonds comprising the chain structure of the proteins.
Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to transfer electrons to a higher energy band such as a more energetic sublevel or energy level. [3] When an excited electron falls back to a state of lower energy, it undergoes electron relaxation (deexcitation [4]).
Ionic bonding can result from a redox reaction when atoms of an element (usually metal), whose ionization energy is low, give some of their electrons to achieve a stable electron configuration. In doing so, cations are formed.
Solvated electrons are involved in the reaction of alkali metals with water, even though the solvated electron has only a fleeting existence. [10] Below pH = 9.6 the hydrated electron reacts with the hydronium ion giving atomic hydrogen, which in turn can react with the hydrated electron giving hydroxide ion and usual molecular hydrogen H 2. [11]
The wave function of fermions, including electrons, is antisymmetric, meaning that it changes sign when two electrons are swapped; that is, ψ(r 1, r 2) = −ψ(r 2, r 1), where the variables r 1 and r 2 correspond to the first and second electrons, respectively. Since the absolute value is not changed by a sign swap, this corresponds to equal ...
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound.It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [1]