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The carbon–fluorine bond is a polar covalent bond between carbon and fluorine that is a component of all organofluorine compounds. It is one of the strongest single bonds in chemistry (after the B–F single bond, Si–F single bond, and H–F single bond), and relatively short, due to its partial ionic character.
The fluorine atoms are located in an alternating fashion above and under the former graphene plane, which is now buckled due to formation of covalent carbon-fluorine bonds. Reaction of carbon with fluorine at even higher temperature successively destroys the graphite compound to yield a mixture of gaseous fluorocarbons such as ...
Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
The carbon–fluorine bond of the smaller molecules is formed in three principal ways: Fluorine replaces a halogen or hydrogen, or adds across a multiple bond. The direct reaction of hydrocarbons with fluorine gas can be dangerously reactive, so the temperature may need to be lowered even to −150 °C (−240 °F). [ 115 ] "
Introducing the carbon–fluorine bond to organic compounds is the major challenge for medicinal chemists using organofluorine chemistry, as the carbon–fluorine bond increases the probability of having a successful drug by about a factor of ten. [30] Over half of agricultural chemicals contain C-F bonds. A common example is trifluralin. [31]
Boron monofluoride or fluoroborylene has the formula BF; Bromine monofluoride, a liquid interhalogen compound with formula BrF; Carbon monofluoride (CF, CF x, or (CF) x), also called polycarbon monofluoride; Chlorine monofluoride, a volatile interhalogen compound with formula ClF; Iodine monofluoride, a chocolate-brown solid compound with ...
Tetrafluoromethane is the product when any carbon compound, including carbon itself, is burned in an atmosphere of fluorine. With hydrocarbons, hydrogen fluoride is a coproduct. It was first reported in 1926. [7] It can also be prepared by the fluorination of carbon dioxide, carbon monoxide or phosgene with sulfur tetrafluoride.
Difluoroacetylene is a compound of carbon and fluorine having molecular formula C 2 F 2. A linear molecule, its two carbons are joined by a triple bond and have terminal fluorines: F-C≡C-F. The molecule is the perfluorocarbon analog of acetylene, C 2 H 2. Preparation of difluoroacetylene is difficult, with danger of explosions and with low ...