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Ceric ammonium nitrate (CAN) is the inorganic compound with the formula (NH 4) 2 [Ce(NO 3) 6]. This orange-red, water-soluble cerium salt is a specialised oxidizing agent in organic synthesis and a standard oxidant in quantitative analysis .
Basic cerium(IV) nitrate has the formula Ce(NO 3) 3.OH.3H 2 O. It also forms upon evaporation of solutions of cerium(IV) in nitric acid. [10] When this meets ammonia in water solution it reacts to form ceric ammonium nitrate and ceric hydroxide. [10] Basic dicerium nitrate has the formula Ce 2 O(NO 3) 6 (H 2 O) 6 ·2H 2 O. Again it crystallizes ...
The compound ceric ammonium nitrate (CAN) (NH 4) 2 [Ce(NO 3) 6] is the most common cerium compound encountered in the laboratory. The six nitrate ligands bind as bidentate ligands . The complex [Ce(NO 3 ) 6 ] 2− is 12-coordinate, a high coordination number which emphasizes the large size of the Ce 4+ ion.
Cerium(III) sulfate is one of the few salts whose solubility in water decreases with rising temperature. [12] Ceric ammonium nitrate. Due to ligand-to-metal charge transfer, aqueous cerium(IV) ions are orange-yellow. [13] Aqueous cerium(IV) is metastable in water [14] and is a strong oxidizing agent that oxidizes hydrochloric acid to give ...
Ammonium cerium(IV) sulfate is an inorganic compound with the formula (NH 4) 4 Ce(SO 4) 4 ·2H 2 O. It is an orange-colored solid. It is an orange-colored solid. It is a strong oxidant, the potential for reduction is about +1.44V.
Cerium(IV) sulfate, also called ceric sulfate, is an inorganic compound. It exists as the anhydrous salt Ce(SO 4) 2 as well as a few hydrated forms: Ce(SO 4) 2 (H 2 O) x, with x equal to 4, 8, or 12. These salts are yellow to yellow/orange solids that are moderately soluble in water and dilute acids.
Ammonium bromide – NH 4 Br [37] Ammonium chromate – [NH 4] 2 CrO 4 [38] Ammonium cerium(IV) nitrate – [NH 4] 2 [Ce(NO 3) 6] Ammonium cerium(IV) sulfate – [NH 4] 4 [Ce(SO 4) 4] Ammonium chloride – [NH 4]Cl [39] Ammonium chlorate – [NH 4]ClO 3 [40] Ammonium cyanide – [NH 4]CN [41] Ammonium dichromate – [NH 4] 2 Cr 2 O 7 [42 ...
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.