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In statistical mechanics, the mean squared displacement (MSD, also mean square displacement, average squared displacement, or mean square fluctuation) is a measure of the deviation of the position of a particle with respect to a reference position over time.
By measuring the mean squared displacement over a time interval along with the universal gas constant R, the temperature T, the viscosity η, and the particle radius r, the Avogadro constant N A can be determined. The type of dynamical equilibrium proposed by Einstein was not new.
The particle's Mean squared displacement from its original position is: =, where is the dimension of the particle's Brownian motion. For example, the diffusion of a molecule across a cell membrane 8 nm thick is 1-D diffusion because of the spherical symmetry; However, the diffusion of a molecule from the membrane to the center of a eukaryotic ...
Mean squared displacement for different types of anomalous diffusion Anomalous diffusion is a diffusion process with a non-linear relationship between the mean squared displacement (MSD), r 2 ( τ ) {\displaystyle \langle r^{2}(\tau )\rangle } , and time.
Simulated squared displacements of free Brownian particles (semi-transparent wiggly lines) as a function of time, for three selected choices of initial squared velocity which are 0, 3k B T/m, and 6k B T/m respectively, with 3k B T/m being the equipartition value in thermal equilibrium. The colored solid curves denote the mean squared ...
Landau–Peierls instability refers to the phenomenon in which the mean square displacements due to thermal fluctuatuions diverge in the thermodynamic limit and is named after Lev Landau (1937) and Rudolf Peierls (1934).
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x is displacement; E(x) is energy; Q is the heat of adsorption or binding energy; a is the spacing between adjacent adsorption sites; E diff is the barrier to diffusion. Surface diffusion kinetics can be thought of in terms of adatoms residing at adsorption sites on a 2D lattice , moving between adjacent (nearest-neighbor) adsorption sites by a ...