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pK a of acetic acid in dioxane/water mixtures. Data at 25 °C from Pine et al. [45] When a compound has limited solubility in water it is common practice (in the pharmaceutical industry, for example) to determine pK a values in a solvent mixture such as water/dioxane or water/methanol, in which the compound is more soluble. [46]
A cement accelerator is an admixture for the use in concrete, mortar, rendering or screeds. The addition of an accelerator speeds the setting time and thus cure time starts earlier. [ 1 ] This allows concrete to be placed in winter with reduced risk of frost damage. [ 2 ]
The ratio Ca/Si (C/S) and Mg/Si (M/S) decrease from 2 for the dicalcium and dimagnesium silicate reagents to 1.5 for the hydrated silicate products of the hydration reaction. In other term, the C-S-H or the serpentine are less rich in Ca and Mg respectively.
Accelerated curing is any method by which high early age strength is achieved in concrete. These techniques are especially useful in the prefabrication industry, wherein high early age strength enables the removal of the formwork within 24 hours, thereby reducing the cycle time, resulting in cost-saving benefits. [ 1 ]
Curing is a chemical process employed in polymer chemistry and process engineering that produces the toughening or hardening of a polymer material by cross-linking of polymer chains. [1] Even if it is strongly associated with the production of thermosetting polymers , the term "curing" can be used for all the processes where a solid product is ...
Oxidation of pyrite in clay formations in contact with concrete – this produces sulfuric acid which reacts with concrete. Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S).
Their addition allows to decrease the water-to-cement ratio of concrete or mortar without negatively affecting the workability of the mixture. It enables the production of self-consolidating concrete and high-performance concrete. The water–cement ratio is the main factor determining the concrete strength and its durability. Superplasticizers ...
[5] [6] [7] In the presence of water (during a rainstorm, for instance) unreacted cement particles recently exposed due to cracking hydrate and form a number of products (calcium silicate hydrates (C-S-H), calcite, etc.) that expand and fill in the crack. These products appear as a white ‘scar’ material filling in the crack.