Search results
Results From The WOW.Com Content Network
In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
For the special case of a gas to which Boyle's law [4] applies, the product pV (p for gas pressure and V for gas volume) is a constant if the gas is kept at isothermal conditions. The value of the constant is nRT, where n is the number of moles of the present gas and R is the ideal gas constant. In other words, the ideal gas law pV = nRT ...
The equation PV = nRT represents the ideal gas law, where P is the pressure of the gas, V is the volume, n is the number of moles, R is the universal gas constant, and T is the temperature. Gibbs's free energy formula
For example, the ideal gas law in terms of the Boltzmann constant is: P V = N k B T , {\displaystyle PV=Nk_{\rm {B}}T,} where N is the number of particles (molecules in this case), or to generalize to an inhomogeneous system the local form holds:
We can solve for the temperature of the compressed gas in the engine cylinder as well, using the ideal gas law, PV = nRT (n is amount of gas in moles and R the gas constant for that gas). Our initial conditions being 100 kPa of pressure, 1 L volume, and 300 K of temperature, our experimental constant (nR) is:
Application examples [ edit ] If one sets out to determine the specific volume of an ideal gas, such as super heated steam, using the equation ν = RT / P , where pressure is 2500 lbf/in 2 , R is 0.596, temperature is 1960 °R .
An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to predict ...