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Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
Because a dalton, a unit commonly used to measure atomic mass, is exactly 1/12 of the mass of a carbon-12 atom, this definition of the mole entailed that the mass of one mole of a compound or element in grams was numerically equal to the average mass of one molecule or atom of the substance in daltons, and that the number of daltons in a gram ...
The Avogadro constant, commonly denoted N A [1] or L, [2] is an SI defining constant with an exact value of 6.022 140 76 × 10 23 mol −1 (reciprocal moles). [3] [4] It is this defined number of constituent particles (usually molecules, atoms, ions, or ion pairs—in general, entities) per mole and used as a normalization factor in relating the amount of substance, n(X), in a sample of a ...
One mole is an aggregate of an Avogadro number of entities, 1 mol = N 0 ent. This means that the appropriate atomic-scale unit for molar mass is dalton per entity, Da/ent = M u, very nearly equal to 1 g/mol. For Da/ent to be exactly equal to g/mol, the dalton would need to be redefined exactly in terms of the (fixed-h) kilogram.
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
The equivalent weight of an element is the mass of a mole of the element divided by the element's valence. That is, in grams, the atomic weight of the element divided by the usual valence. [2] For example, the equivalent weight of oxygen is 16.0/2 = 8.0 grams.
The dalton (symbol: Da) is the standard unit that is used for indicating mass on an atomic or molecular scale (atomic mass). [1] The unified atomic mass unit (symbol: u) is equivalent to the dalton. One dalton is approximately the mass of one a single proton or neutron. [2] The unified atomic mass unit has a value of 1.660 538 921 (73) × 10 ...
Since free protons and neutrons differ from each other in mass by a small fraction of a dalton (1.388 449 33 (49) × 10 −3 Da), [9] rounding the relative isotopic mass, or the atomic mass of any given nuclide given in daltons to the nearest whole number, always gives the nucleon count, or mass number.