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To determine if the parameters of two molecules (usually a solvent and a polymer) are within range, a value called interaction radius is given to the substance being dissolved. This value determines the radius of the sphere in Hansen space and its center is the three Hansen parameters.
Another application of polymer solutions includes the manufacture of fibers by wet or dry spinning or plastic films. Disadvantages of solution polymerization are decrease of monomer and initiator concentration leading to reduction of reaction rate, lower volume utilization of reactor, additional cost of the process related to solvent recycling ...
A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules, and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell. Major uses of solvents are in paints, paint removers, inks, and dry cleaning. [2]
In addition to over 130 published papers and 8 patents (h-index 25), he authored Hansen Solubility Parameters – A User's Handbook in 1999 followed by an expanded 2nd Edition in 2007. [6] With Abbott and Yamamoto he authored the package of software, eBook, and datasets called Hansen Solubility Parameters in Practice, in 2008 which is currently ...
These may be liquid solutions (e.g. in aqueous solution), or solid solutions (e.g. a substance which has been plasticized). [2] The introduction into the polymer of small amounts of a solvent (plasticizer) reduces the temperature of glass transition, the yield temperature, and the viscosity of a melt.
In polymer science, dispersion polymerization is a heterogeneous polymerization process carried out in the presence of a polymeric stabilizer in the reaction medium. . Dispersion polymerization is a type of precipitation polymerization, meaning the solvent selected as the reaction medium is a good solvent for the monomer and the initiator, but is a non-solvent for the po
Bulk polymerization is carried out in the absence of any solvent or dispersant and is thus the simplest in terms of formulation. It is used for most step-growth polymers and many types of chain-growth polymers. In the case of chain-growth reactions, which are generally exothermic, the heat evolved may cause the reaction to become too vigorous ...
In a polymer solution, a theta solvent (or θ solvent) is a solvent in which polymer coils act like ideal chains, assuming exactly their random walk coil dimensions. [ clarification needed ] Therefore, the Mark–Houwink equation exponent is 1 / 2 {\displaystyle 1/2} in a theta solvent.